Silicone Surface-Treated Powders for Cosmetics
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It was more than 30 years ago that silicone oil began to use for coating the surface of powder particles. This invention led to the development of two-way foundation powder which can be resistant to both oil and water. Sweatproof and waterproof makeup was the further development in this field, which has been mainly intended for women in sporty occasion.
Silicone surface-treated powders are excellent in their water repellency and dispersibility, which has been widely used as a functional filler in cosmetic products.
Schematic image of silicone surface-treated powder:
Lineup:
| Items | Chemical names |
|---|---|
| HD-2 TALC JA-46R | Hydrogen dimethicone, Talc (Asbestos free Talc) |
| HD-2 TIO2 CR-50 | Hydrogen dimethicone, Titanium, Dioxide, Aluminum Hydroxide |
| HD-2 YELLOW LLXLO | Hydrogen dimethicone, Iron Oxide |
| HD-2 RED R-516L | Hydrogen dimethicone, Iron Oxide |
| HD-2 BLACK BL-100 | Hydrogen dimethicone, Iron Oxide |
| HD-2 SERICITE FSE | Hydrogen dimethicone, Sericite |
| HD-2 MICA Y-2300 | Hydrogen dimethicone, Mica |
Note: HD-2 stands for “2% Hydrogen Dimethicone”.
Features:
Water repellency: HD-2 TALC JA-46R
If offers excellent water repellency
when agitating with the stirrer.
The products have been certified by HALAL certification authority.
Formulation examples:
- Compact Cake Foundation (2-way cake)
- Pressed Powder
- Oil Cake Foundation
- Mascara
- Water Proof Eye Liner
- Liquid Foundation (Shake well)
- Cream Foundation
- BB Cream
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 24.24 | HD-2 TALC JA-46R |
| 2 | 8.50 | HD-2 TIO2 CR-50 | |
| 3 | 15.00 | HD-2 MICA Y-2300 | |
| 4 | 30.00 | HD-2 SERICITE FSE | |
| 5 | 3.00 | Silicone-treated spherical silica | |
| 6 | 5.00 | Corn starch (JAPAN CORN STRACH) | |
| 7 | 1.80 | HD-2 YELLOW LLXLO | |
| 8 | 0.35 | HD-2 RED R-516L | |
| 9 | 0.10 | HD-2 BLACK BL-100 | |
| B | 10 | 6.00 | Dimethicone (500/1000cs) |
| 11 | 2.00 | Triethylhexanorin: T.I.O (Nisshin Oillio) | |
| 12 | 4.00 | Squalene | |
| 13 | 0.01 | Tocopherol (Nisshin Oillio) | |
| 14 | Optimum | Preservative | |
| Total | 100.00 | ||
[Procedures]
- Mix 1 to 9, and pulverize them (Phase A).
- Evenly mix 10 to 14 (Phase B), and mix with A, and pulverize the mixture.
- Sieve the mixture, compress and mold it into a plate.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 61.88 | HD-2 TALC JA-46R |
| 2 | 1.80 | HD-2 TIO2 CR-50 | |
| 3 | 18.00 | HD-2 MICA Y-2300 | |
| 4 | 2.70 | Lauroyl Lysine: Amihope LL (AJINOMOTO) | |
| 5 | 4.50 | Titanium Dioxide coated mica | |
| 6 | 0.90 | HD-2 YELLOW LLXLO | |
| 7 | 0.14 | HD-2 RED R-516L | |
| 8 | 0.07 | HD-2 BLACK BL-100 | |
| 9 | 0.01 | Methylparaben | |
| B | 10 | 5.00 | Dimethicone (500/1000cs) |
| 11 | 1.70 | Neopentyl Glycol Diethylhexanoate: SALACOS 525 (Nisshin Oillio) | |
| 12 | 0.30 | Dipentaerythrityl Hexahydroxystearate/Hexastearate/Hexarosinate: COSMOL 168ARV (Nisshin Oiilio) |
|
| 13 | 2.98 | Squalene | |
| 14 | 0.01 | Tocopherol (Nisshin Oillio) | |
| 15 | 0.01 | Propylparaben | |
| Total | 100.00 | ||
[Procedures]
- Mix 1 to 9, and pulverize them (Phase A).
- Evenly mix 10 to 15, and dissolve them by heating (Phase B).
- Mix A and B and pulverize further.
- Sieve the mixture, and mold it into a plate such as a metal tray.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 40.00 | HD-2 TALC JA-46R |
| 2 | 12.00 | HD-2 TIO2 CR-50 | |
| 3 | 3.50 | Silicone-treated spherical silica | |
| 4 | 3.00 | HD-2 YELLOW LLXLO | |
| 5 | 0.70 | HD-2 RED R-516L | |
| 6 | 0.20 | HD-2 BLACK BL-100 | |
| B | 7 | 36.00 | Isocetyl myristate |
| 8 | 1.50 | Polyglyceryl-6 Polyricinoleate | |
| 9 | 1.00 | Carnauba wax (Cerarica Noda) | |
| 10 | 1.00 | Candelilla Wax (Cerarica Noda) | |
| 11 | 0.10 | Tocopherol (Nisshin Oillio) | |
| 12 | Optimum | Preservative | |
| C | 13 | 1.00 | Cyclomethicone |
| 100.00 | |||
[Procedures]
- Mix 1 to 6, and pulverize them (Phase A)
- Dissolve 7 to 12 by heating (Phase B), and add A to B, and disperse it evenly.
- Add 13 (Phase C) to the above A+B, and mold it into a plate.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 2.00 | Hydrogenated Polyisobutene (NOF) |
| 2 | 35.65 | Isododecane | |
| 3 | 20.00 | Isohexadecane | |
| 4 | 5.00 | Trimethylsiloxysilicate | |
| 5 | 5.00 | Cyclopentasiloxane | |
| 6 | 15.00 | Dextrin Palmitate | |
| 7 | 2.00 | Microcrystalline wax | |
| 8 | 3.00 | Polyethylene | |
| 9 | 0.05 | Tocopherol (Nisshin Oillio) | |
| 10 | 0.20 | Propylparaben | |
| B | 11 | 3.60 | HD-2 TALC JA-46R |
| 12 | 8.00 | HD-2 BLACK BL-100 | |
| C | 13 | 0.50 | Silica Dimethyl Silylate |
| Total | 100.00 | ||
[Procedures]
- Weigh 1 to 10, and dissolve them by heating. (Phase A)
- Weigh and mix 11 and 12, and pulverize them. (Phase B)
- Add B and 13 (Phase C) to A, stir the mixture to be uniform.
- Cool it down to a room temperature, and fill it in a container.
| (Wt %) | Ingredients | |
|---|---|---|
| 1 | 50.00 | Acrylates/Dimethicone Copolymer, Isopropyl Alcohol |
| 2 | 17.30 | Trimethylsiloxysilicate, Cyclopentasiloxane |
| 3 | 0.20 | Antiseptic |
| 4 | 2.50 | Quaternium-18 Hectorite (Kunimine) |
| 5 | 19.20 | Isododecane |
| 6 | 0.80 | Propylene Carbonate |
| 7 | 10.00 | HD-2 BLACK BL-100 |
| Total | 100.00 |
[Procedures]
- Mix 4, 5 and 6, and stir them at 5000 rpm for 3 minutes.
- Mix 1, 2 and 3, and add them to the above (1), and stir the mixture at 5000 rpm for 3 minutes.
- Add 7 to the above mixture of (1) and (2), and stir the mixture at 5000 rpm for 3 minutes.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 2.00 | PEG-10 dimethicone |
| 2 | 0.60 | Sorbitan sesquiisostearate: COSMOL 182V (Nisshin Oillio) | |
| 3 | 2.00 | Neopentyl glycol diethylhexanoate: COSMOL 525 (Nisshin Oillio) | |
| 4 | 2.00 | Pentaerythrityl tetraethylhexanoate: SALACOS 5408 (Nisshin Oillio) | |
| 5 | 1.00 | Squalane | |
| 6 | 4.00 | Ethylhexyl methoxycinnamate | |
| 7 | 0.50 | Diethylamino hydroxybenzoyl hexyl benzoate | |
| 8 | 0.05 | Tocopherol | |
| B | 9 | 25.00 | Cyclomethicone |
| C | 10 | 0.30 | Dimethicone |
| 11 | 5.50 | Cyclomethicone | |
| 12 | 1.13 | Disteardimonium hectorite | |
| 13 | 0.55 | Ethanol | |
| 14 | 0.02 | Water | |
| D | 15 | 8.70 | HD-2 TALC JA-46R |
| 16 | 6.00 | HD-2 TIO2 CR-50 | |
| 17 | 4.00 | Spherical silica: Godd Ball G-6C (Suzuki Yushi) | |
| 18 | 4.00 | Micro Titanium Dioxide: STR-100C-LF (Sakai Chemical) | |
| 19 | 1.00 | HD-2 YELLOW LLXLO | |
| 20 | 0.20 | HD-2 RED R-516L | |
| 21 | 0.10 | HD-2 BLACK BL-100 | |
| E | 22 | 23.55 | Water |
| 23 | 6.00 | BG: 1,3-Butylene Glycol (Daicel) | |
| 24 | 1.00 | Glycerin | |
| 25 | 0.20 | Phenoxyethanol | |
| 26 | 0.30 | Sodium chloride | |
| 27 | 0.30 | Silica (Hydrophilic fumed silica) | |
| Total | 100.00 | ||
[Procedures]
- Mix (10)～(14) until evenly dispersed. (Phase C)
- Mix and pulverize (15)～(21). (Phase D)
- Add (1)～(8) in the main container and dissolve the mixture by heating, then add (9) to it. (Phase A+B)
- Mix A+B, with C and D, and mix them all by a homogenizer until evenly dispersed.
- Mix (22)～(27) well (Phase E), and add E to the above mixture of A+B+C+D, and emulsify them by using a homomixer.
- Cool it down to a room temperature while stirring, and fill it in a package.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 3.00 | Lauryl PEG/PPG-18/18 methicone |
| 2 | 1.00 | PEG-10 glyceryl triisostearate: EMALEX GWIS-310 (Nihon Emulsion) | |
| 3 | 1.00 | Squalane | |
| 4 | 1.00 | Glyceryl behenate/eicosadioate: NOMCORT HK-G (Nisshin Oillio) | |
| 5 | 3.00 | Neopentyl glycol dicaprate: ESTEMOL N-01 (Nisshin Oillio) | |
| 6 | 3.00 | Neopentyl glycol diethylhexanoate: COSMOL 525 (Nisshin Oillio) | |
| 7 | 2.00 | Pentaerythrityl tetraethylhexanoate: SALACOL 5408 (Nisshin Oillio) | |
| 8 | 1.00 | Diethylamino hydroxybenzoyl hexyl benzoate | |
| 9 | 1.50 | Stearoyl inulin | |
| 10 | 4.00 | Ethylhexyl methoxycinnamate | |
| 11 | 0.05 | Tocopherol | |
| B | 12 | 14.50 | Cyclopentasiloxane |
| C | 13 | 6.00 | HD-2 TIO2 CR-50 |
| 14 | 3.88 | HD-2 TALC JA-46R | |
| 15 | 9.00 | Spherical silica: Godd Ball G-6C (Suzuki Yushi) | |
| 16 | 0.80 | HD-2 YELLOW LLXLO | |
| 17 | 0.20 | HD-2 RED R-516L | |
| 18 | 0.10 | HD-2 BLACK BL-100 | |
| D | 19 | 36.47 | Water |
| 20 | 6.00 | BG: 1,3-Butylene Glycol (Daicel) | |
| 21 | 1.00 | Glycerin | |
| 22 | 0.50 | Phenoxyethanol | |
| 23 | 1.00 | Sodium chloride | |
| Total | 100.00 | ||
[Procedures]
- Mix and pulverize (13)～(18). (Phase C)
- Add (1)～(11) in the main container and dissolve the mixture by heating, then add (12) to it. (Phase A+B)
- Add A+B to C, and mix them all by a homogenizer until evenly dispersed.
- Mix (19)～(23) well (Phase D), and add D to the above mixture of A+B+C, and emulsify them by using a homomixer.
- Cool it down to a room temperature while stirring, and fill it in a package.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 8.00 | Cyclopentasiloxane |
| 2 | 4.00 | Paraffin liquid | |
| 3 | 4.00 | Ethylhexyl methoxycinnamate | |
| 4 | 1.00 | Sorbitan isostearate | |
| 5 | 2.00 | Lauryl PEG-9 polydimethylsiloxyethyl dimethicone | |
| 6 | 2.00 | Tribehenin | |
| 7 | 1.00 | Petrolatum | |
| 8 | 1.00 | Propylene glycol dicaprylate/Dicaprate | |
| 9 | 1.00 | Phenyl trimethicone | |
| 10 | 2.00 | Dimethicone/Vinyl dimethicone crosspolymer, cycolpentasiloxane | |
| B | 11 | 5.00 | HD-2 TALC JA-46R |
| 12 | 1.00 | Polymethylsilsesquioxane | |
| 13 | 5.00 | HD-2 TIO2 CR-50 | |
| 14 | 1.00 | HD-2 YELLOW LLXLO | |
| 15 | 0.20 | HD-2 RED R-516L | |
| 16 | 0.10 | HD-2 BLACK BL-100 | |
| C | 17 | 4.00 | Dipropylene glycol |
| 18 | 3.00 | Maltitol | |
| 19 | 1.00 | Glycerin | |
| 20 | 1.00 | Sorbitol | |
| 21 | 52.20 | Water | |
| 22 | 0.50 | Sodium chloride | |
| 23 | Optional | Preservative | |
| Total | 100.00 | ||
[Procedures]
- Mix and pulverize (11)～(16). (Phase B)
- Add (2)～(10) in the main container and dissolve the mixture by heating, then add (1) to it. (Phase A)
- Add B to A, and mix them by a homogenizer until evenly dispersed.
- Mix (17)～(23) well (Phase C), and add C to the above mixture of A+B, and emulsify them by using a homomixer.
- Cool it down to a room temperature while stirring, and fill it in a package.
| (Wt %) | Ingredients | ||
|---|---|---|---|
| A | 1 | 7.00 | Palmitic acid |
| 2 | 5.00 | Stearic acid | |
| 3 | 3.00 | Dimethicone | |
| 4 | 0.50 | Cetylalcohol | |
| 5 | 1.40 | Glycery Stearate SE | |
| 6 | 6.00 | Ethylhexyl p-Methoxycinnamate | |
| 7 | 2.00 | Diethylamino Hydroxybenzoyl Hexyl Benzoate | |
| B | 8 | 9.50 | Isopropyl Myristate |
| 9 | 0.40 | Isostearic acid | |
| 10 | 2.00 | HD-2 TIO2 CR-50 | |
| C | 11 | 20.0 | Ammonium acryloyldimethyl taurate / VP copolymer, Water |
| 12 | 0.10 | Niacinamide | |
| 13 | 0.40 | Potassium Hydroxide | |
| 14 | 2.00 | Glycerin | |
| 15 | 4.00 | Butylene Glycol | |
| 16 | 0.20 | Methyl Paraben | |
| 17 | 0.20 | Phenoxy Ethanol | |
| 18 | 36.3 | Water | |
| Total | 100.00 | ||
[Procedures]
- A. Combine ⑧（0.5g）、⑨、⑩ with three rolls
- B. Combine ①－⑦、⑧（9g）、A with stirring and heat to 80℃.
- C. Combine ⑪－⑱ with stirring and heat to 80℃.
- D. Add B to C with stirring.
Disclaimer:
Formulation examples shown herein are construed as a standard indicator without any liability to us for the result of production. Please be aware that certain unwritable technical issues and the possibility of a patent infringement should be involved in the information.
